• P-ISSN2233-4203
  • E-ISSN2093-8950

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  • P-ISSN 2233-4203
  • E-ISSN 2093-8950

Application of Comprehensive 2D GC-MS and APPI FT-ICR MS for More Complete Understanding of Chemicals in Diesel Fuel

Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2012, v.3 no.2, pp.43-46
https://doi.org/10.5478/MSL.2012.3.2.43
Cho Yunju (Kyungpook National University)
Annana Islam (Kyungpook National University)
Arif Ahmed (Kyungpook National University)
Kim Sunghwan (Kyungpook National University)
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Abstract

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples.

keywords
2D GC-MS High resolution mass spectrometry FT-ICR MS Oil


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Submission Date
2012-06-08
Revised Date
2012-06-17
Accepted Date
2012-06-17
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