Article Detail

Home > Article Detail
  • P-ISSN 2233-4203
  • E-ISSN 2093-8950

Application of Comprehensive 2D GC-MS and APPI FT-ICR MS for More Complete Understanding of Chemicals in Diesel Fuel

Mass Spectrometry Letters / Mass Spectrometry Letters, (P)2233-4203; (E)2093-8950
2012, v.3 no.2, pp.43-46
https://doi.org/10.5478/MSL.2012.3.2.43
Cho Yunju (Kyungpook National University)
Annana Islam (Kyungpook National University)
Arif Ahmed (Kyungpook National University)
Kim Sunghwan (Kyungpook National University)
  • Downloaded
  • Viewed

Abstract

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples.

keywords
2D GC-MS, High resolution mass spectrometry, FT-ICR MS, Oil


Reference

1

Silva, S. L. (2011). . Anal. Chimi. Acta, 707, 18-.

2

Ai-Thamir, W. K. (1988). . Fuel, 67, 871-.

3

Müller, A. L. H. (2012). . Spectro. Acta Part A: Mol. and Biomol. Spectro, 89, 82-.

4

Genov, G. (2008). . Org. Geochem, 39, 1229-.

5

Li, M. (2002). . Coll. and Surf. A: Phys. and Eng. Asp, 197, 193-.

6

Wang, Z. D. (2006). . Env. Foren, 7, 105-.

7

Marriott, P. J. (2001). . Chromatogr. A, 936, 1-.

8

Tabanca, N. (2005). . J. Chromatogr. A, 1097, 192-.

9

Dallüge, J. (2003). . J. Chromatogr. A, 1000, 69-.

10

Marriott, P. (2002). . TrAC Trends Anal. Chem, 21, 573-.

11

Marshall, A. G. (1985). . Acc. Chem. Res, 18, 316-.

12

Maikhunthod, B. (2010). . J. Chromatogr. A, 1217, 1522-.

13

Dutriez, T. (2010). . Fuel, 89, 2338-.

14

Flego, C. (2011). . Fuel, 90, 2863-.

15

Marsman, J. H. (2007). . J. Chromatogr. A, 1150, 21-.

16

Nizio, K. D. . J. Chromatogr. A, , -.

17

Eunkyoung Kim. (2011). Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry. Mass Spectrometry Letters, 2(2), 41-44. http://dx.doi.org/10.5478/MSL.2011.2.2.041.

18

Marshall, A. G. (1998). . Mass Spec. Rev, 17, 1-.

19

Rodgers R. P. (2002). . Fuel Chem. Div. Prep, 47, 636-.

20

Wang, J. (2011). . Chemosphere, 85, 609-.

21

Hughey, C. A. (2002). . Org. Geochem, 33, 743-.

22

Helms, J. R. (2012). . Org. Geochem, 44, 21-.

23

Miyabayashi, K. (2008). . Fuel Pro.Tech, 89, 397-.

24

Hur, M. (2009). (-). Interpretation of Crude Oil High Resolution Spectra obtained by ESI and APPI FT-ICR Mass Spectrometry using Principal Components Analysis In 57th ASMS Conference on Mass Spectrometry and Allied Topics.

25

Manhoi Hur. (2009). Optimized Automatic Noise Level Calculations for Broadband FT-ICR Mass Spectra of Petroleum Give More Reliable and Faster Peak Picking Results. Bulletin of the Korean Chemical Society, 30(11), 2665-2668.

26

Reichenbach, S. E. (2004). . Chemo. and Intell. Lab. Sys, 71, 107-.

27

Murphy, R. E. (1998). . Anal. Chem, 70, 1585-.

28

Reichenbach, S. E. (2003). . J. Chromatogr. A, 985, 47-.

29

Kallio, M. (2007). . J. Chromatogr. A, 1148, 228-.

30

Vendeuvre, C. (2005). . J. Chromatogr. A, 1086, 21-.

31

Adam, F. (2008). . J. Chromatogr. A, 1186, 236-.

32

Cookson, D. J. (1987). . Fuel, 66, 758-.

33

Dutriez, T. (2012). . Fuel, 96, 108-.

34

Adahchour, M. (2006). . TrAC Tren. in Anal. Chem, 25, 726-.

Submission Date
2012-06-08
Revised Date
2012-06-17
Accepted Date
2012-06-17
상단으로 이동

Mass Spectrometry Letters